by S. Götz, D. Li, V. Kolb, J. Pflaum, and T. Brixner
just been published in Optics Express.
Locally resolved non-linear spectroscopy on nanostructured surfaces reveals important information on the microscopic excitation processes as well as on the effects of structural homogeneity on the emission characteristics. In this publication, a newly developed coherent 2D fluorescence micro-spectroscopy setup with sub-micron resolution is presented and has been successfully tested on hexagonally patterned perfluorinated zinc-phthalocyanine (F16ZnPc) nanopillars of about 200 nm in size and 500 nm in lattice constant. As it was demonstrated, the rephasing, non-rephasing and absorptive 2D spectra could be reconstructed and related to the local morphology of the structured surface and its lateral disturbances. The technique reported is thus capable of detecting the nonlinear response in chromophoric systems and their couplings to the close proximity.
By a successful and scientifically highly exciting oral defence, Florian Hüwe finished his PhD in our group on July 26th. In his thesis titled: 'Electrothermal Investigation of Charge and Heat Transport in the Low-Dimensional Organic Conductor (DCNQI)2Cu' he analyses the electrical and thermal properties of archetypical low-dimensional organic metals and demonstrates their potential for future thermoelectric applications.
Congratulations and all the best for your future at Zeiss Semiconductor Manufactoring Technology!
by C. Brückner. M. Stolte, F. Würthner, J. Pflaum, B. Engels
has just been accepted for publication in the Journal of Physical Organic Chemistry.
In this work, masterminded by the colleagues from theoretical chemistry, the effect of energetic disorder occuring in the vicinity of interfaces in amorphous organic heterostructures has been analyzed in great detail for various molecular semiconductors by extended calculations on the QM/MM level. Variations of ground-, excited-, and cationic-state energies as well as of ionization potentials and excitation energies unambiguosly corroborate the importance of this physical quantity on the charge and exciton transport and thus, on the opto-electronic performance of organic thin film devices.
Congratulations to Michael Brendel. On July 7, he successfully defended his doctoral thesis on the topic of "Correlation between Interface Energetics of Molecular Semiconductors and Opto-Electronic Properties of Planar Organic Solar Cells". We wish him best luck for the future and hope that he can benefit from his knowledge gained on interface and thin film physics also at his new job at Zeiss Semiconductor Manufactoring Technology.
New publication on "Energy Losses in Small-Molecule Organic Photovoltaics"
by T. Linderl, T. Zechel, M. Brendel, D. Moseguí González, P. Müller-Buschbaum, J. Pflaum, W. Brütting
in Advanced Energy Materials
Energy losses play an important role in the performance of organic photovoltaic cells, but up-to-date, are not completely understood on microscopic scales. In this contribution, which emerged from a collaborative work of the universities in Augsburg, Munich and Wuerzburg within the "Solar Technologies Go Hybrid (SolTech)" project of the Bavarian Government, we address this fundamental question by analyzing the impact of charge-transfer states generated at molecular donor/acceptor interfaces on the resulting device parameters, in particular, the open-circuit voltage.
We congratulate Benedikt Stender on his successful PhD thesis defense on the topic of "Single photon emitters and their interactions with charge carriers in organic light emitting diodes".
Our latest manuscript on the topic "Hybrid metal-organic nanocavity arrays for efficient light out-coupling"
by V. Kolb and J. Pflaum
has been published in Optics Express.
We investigated the light outcoupling of periodically ordered hybrid metal/organic nanocavities by means of confocal photoluminescence microscopy. We were able to distinguish between plasmonic and geometrical contributions to the overall emission enhancement compared to unstructured thin films. Supporting TCSPC measurements revealed an exciton lifetime reduction of at least one order of magnitude, consistent with the plasmonic contribution to an areal emission enhancement up to 700.
Our latest manuscript with the topic "Low-Cost and Sustainable Organic Thermoelectrics Based on Low-Dimensional Molecular Metals"
by F. Huewe, A. Steeger, K. Kostova, L. Burroughs, I. Bauer, P. Strohriegl, V. Dimitrov, S. Woodward, and J. Pflaum
has been published in Advanced Materials.
In this contribution we investigate the material class of low-dimensional organic conductors with respect to their thermoelectric application potential. The molecular metals DCNQI2Cu (n-type) and TTT2I3 (p-type) not only reveal appreciable thermoelectric performance at room temperature but even outperform conventional inorganic thermoelectrics at cryogenic temperatures. A thermoelectric generator built of the two materials reveals areal power outputs of unprecendented magnitude in organic thermoelectrics.
Congratulations to Nis Hauke Hansen on the successful defense of his PhD thesis entitled "Microscopic charge transport mechanisms and exciton annihilation in organic thin films and single crystals"!
We welcome the new PhD students in our group! Sebastian Hammer joined our group already in July after finishing his graduate thesis in Experimental Physics 5. Thomas Ferschke remains for his PhD thesis in our group after submitting his master thesis on "Photoluminescence Studies on Tetraphenyldibenzoperiflanthene (DBP) Guest Molecules in Tris(8-hydroxyquinolinato)aluminum (Alq3) Based Light Emitting Diodes". We wish you fun and success during your studies here!
Again we finished the ChemCup 2016 football tournament as best physics team! Special thanks to the organizers as well as every member of our outstanding team!
We congratulate Anna Katharina Topczak on succesfully defending her PhD thesis on "Mechanisms of the exciton transport and its dynamics in molecular thin films for organic photovoltaic applications".
Congratulations to Andreas Steindamm on defending his PhD thesis with the title "Excitonic loss mechanisms in organic bilayer solar cells"!
We published a new article on the "Energy exchange between phononic and electronic subsystems governing the nonlinear conduction in DCNQI2Cu"
by Florian Huewe, Alexander Steeger, Irene Bauer, Steffen Doerrich, Peter Strohriegl and Jens Pflaum
in Physical Review B.
Our dynamical analysis of the resistive switching in the low-dimensional organic conductor DCNQI2Cu revealed a nonequilibrium optical phonon population by efficient interaction with the charge-carrying entity. Therefore, we extended the electrothermal model by a multiplication channel of charge-carriers via optical phonons leading to the nonlinear conduction in DCNQI2Cu.
Our new publication on "Diketopyrrolopyrroles with a Distinct Energy Level Cascade for Efficient Charge Carrier Generation in Organic Solar Cells"
by Christian J. Mueller, Michael Brendel, Pia Ruckdeschel, Jens Pflaum and Mukundan Thelakkat
has been published in Advanced Energy Materials.
By tuning the electron deficiency of the terminal aryl unit of low molecular weight diketopyrrolopyrrole compounds a defined modification of their frontier orbital energies is established. Utilizing these compounds in cascade solar cells in combination with the electron acceptor C60 yields a huge increase of the short circuit current densities and power conversion efficiencies in comparison to the corresponding bilayer devices.
Our new paper on "The Effect of Gradual Fluorination on the Properties of FnZnPc Thin Films and FnZn Pc/C60 Bilayer Photovoltaic Cells"
by M. Brendel, S. Krause, A. Steindamm, A. K. Topczak, S. Sundarraj, P. Erk, N. Koch, J. Pflaum
has been published in Advanced Functional Materials.
The impact of gradually fluorinated zinc phthalocyanine molecules on the opto-electronic properties of FnZnPc/C60 bilayer solar cells is investigated. Upon increasing the degree of fluorination, distinct variations of the cell parameters such as the open circuit voltage and the short circuit current density are detected. In combination with complementary photoluminescence and ultraviolet photoelectron spectroscopy measurements a detailed picture of the relevant donor/acceptor interface energetics and processes evolving on microscopic length scales is developed.